Neco 2022 Chemistry Question 8

Practice essay / theory question 8 from the 2022 Neco Chemistry examination. This question covers solubility, solubility_product, common_ion_effect, experimental_error .

Neco 2022 Chemistry Essay / Theory
Topics: solubility solubility_product common_ion_effect experimental_error
Question 8 NECO • 2022 • CHEMISTRY • essay

The laboratory set‑up shown in the diagram is used to determine the solubility of calcium hydroxide, Ca(OH)₂, at 25 °C. The apparatus consists of a 250 mL beaker containing 200 mL of distilled water, a thermometer, a magnetic stirrer, a filter funnel fitted with filter paper, and a graduated cylinder. In the experiment, excess solid Ca(OH)₂ is added to the water and the mixture is stirred until no more solid dissolves (saturation). The suspension is filtered, and the filtrate is collected in the graduated cylinder. The following data are recorded: - Initial mass of Ca(OH)₂ added: 1.00 g - Mass of undissolved Ca(OH)₂ after filtration: 0.65 g - Volume of filtrate collected: 180 mL - Temperature of the solution: 25 °C Answer the questions below.

Question Parts

( a )
Calculate the solubility of Ca(OH)₂ in grams per 100 mL of water at 25 °C.
( b )
Using the solubility obtained in part (a), calculate the solubility product constant (Ksp) of Ca(OH)₂ at 25 °C. (Assume the dissolution equilibrium: Ca(OH)₂ \(\rightleftharpoons\) Ca²⁺ + 2 OH⁻.)
( c )
Discuss two experimental factors shown in the apparatus that could cause the calculated Ksp to differ from the literature value.
( d )
A 0.10 M NaOH solution is added to 50.0 mL of the saturated Ca(OH)₂ solution obtained above. (i) Predict qualitatively how the solubility of Ca(OH)₂ will change and explain using the common‑ion effect. (ii) Assuming the added NaOH does not change the total volume appreciably, calculate the new equilibrium concentration of Ca²⁺ ions.
( ) Predict qualitatively how the solubility of Ca(OH)₂ will change and explain using the common‑ion effect.
( ) Calculate the new equilibrium concentration of Ca²⁺ ions.

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About This Question

This is Neco 2022 Chemistry Question 8. It is one of the essay questions from the 2022 Neco Chemistry examination.

The question covers solubility, solubility_product, common_ion_effect, experimental_error .

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