Neco 2021 Chemistry Question 8

Practice essay / theory question 8 from the 2021 Neco Chemistry examination. This question covers solubility, solubility product (Ksp), temperature effect on solubility, common ion effect, percent dissolution .

Neco 2021 Chemistry Essay / Theory
Topics: solubility solubility product (Ksp) temperature effect on solubility common ion effect percent dissolution
Question 8 NECO • 2021 • CHEMISTRY • essay

A student is required to determine the solubility of lead(II) chloride (PbCl\(_2\)) in water at 25 °C using the experimental setup shown in the diagram. The apparatus consists of a 250 mL beaker containing distilled water, a clean funnel fitted with filter paper, a pre‑weighed dry crucible, a balance accurate to 0.01 g, and a heating mantle. The student adds excess solid PbCl\(_2\) (5.00 g) to the beaker, gently heats the mixture to maintain a constant temperature of 25 °C, and stirs until no more solid dissolves. The mixture is then filtered, and the filtrate is transferred to the pre‑weighed crucible, which is subsequently dried in an oven at 105 °C to constant mass. The mass of the empty crucible is 12.34 g and the mass of the crucible containing the dried residue is 13.19 g.

Question Parts

( a )
Calculate the solubility of PbCl\(_2\) in water at 25 °C expressed as grams of PbCl\(_2\) dissolved per 100 mL of solution. Show all steps.
( b )
Given that the standard enthalpy change for the dissolution of PbCl\(_2\) is \(\Delta H^{\circ}_{\text{sol}} = +45\) kJ mol\(^{-1}\) (endothermic), predict qualitatively how the solubility will change if the temperature is raised to 40 °C. Use the van’t Hoff relation to estimate the ratio \(K_{40}/K_{25}\).
( c )
Explain the common‑ion effect that would occur if 0.10 M NaCl were added to the saturated PbCl\(_2\) solution. Indicate how the solubility expression and the concentration of dissolved Pb\(^{2+}\) would be affected.
( d )
Determine the percentage of the initially added PbCl\(_2\) that remained undissolved after the experiment.

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About This Question

This is Neco 2021 Chemistry Question 8. It is one of the essay questions from the 2021 Neco Chemistry examination.

The question covers solubility, solubility product (Ksp), temperature effect on solubility, common ion effect, percent dissolution .

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