Neco 2020 Chemistry Question 20

Practice objective / multiple choice question 20 from the 2020 Neco Chemistry examination.

Neco 2020 Chemistry Objective / Multiple Choice Hard Difficulty
Question 20 NECO • 2020 • CHEMISTRY • objective

Two carboxylic acids, acetic acid (CH_{3}COOH) and benzoic acid (C_{6}H_{5}COOH), are each reacted separately with excess ethanol under identical acid‑catalysed conditions at 25\,°C to give the corresponding ethyl esters. The equilibrium constant for the esterification reaction, expressed as K_{eq}=\frac{[\text{ester}][\text{H_{2}O}]}{[\text{acid}][\text{EtOH}]}, is 4.0 for acetic acid and 0.5 for benzoic acid. Assuming the initial concentration of each acid is 0.10\,M, ethanol is present in large excess (its activity may be taken as 1), and the water concentration remains negligible, (a) calculate the equilibrium concentration of each ester, and (b) state which acid gives the higher percent conversion to ester.

Answer Options

Correct Answer A. Acetic acid: [ester]=0.080\,M (80\% conversion); Benzoic acid: [ester]=0.033\,M (≈33\% conversion). Acetic acid gives the higher conversion.
B. Acetic acid: [ester]=0.050\\,M (50\\% conversion); Benzoic acid: [ester]=0.040\\,M (≈40\\% conversion). Benzoic acid gives the higher conversion.
C. Acetic acid: [ester]=0.067\\,M (≈67\\% conversion); Benzoic acid: [ester]=0.025\\,M (≈25\\% conversion). Acetic acid gives the higher conversion.
D. Acetic acid: [ester]=0.090\\,M (90\\% conversion); Benzoic acid: [ester]=0.045\\,M (≈45\\% conversion). Acetic acid gives the higher conversion.
Correct Answer
A
Correct Option:
Acetic acid: [ester]=0.080\,M (80\% conversion); Benzoic acid: [ester]=0.033\,M (≈33\% conversion). Acetic acid gives the higher conversion.

About This Question

This is Neco 2020 Chemistry Question 20. It is one of the objective questions from the 2020 Neco Chemistry examination.

Difficulty level: Hard .

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