Neco 2017 Chemistry Question 41

Practice objective / multiple choice question 41 from the 2017 Neco Chemistry examination.

Neco 2017 Chemistry Objective / Multiple Choice Hard Difficulty
Question 41 NECO • 2017 • CHEMISTRY • objective

Metal X forms the oxide XO. The standard enthalpy of formation of XO is \(-350\ \text{kJ mol}^{-1}\) and the standard entropy of formation is \(-120\ \text{J mol}^{-1}\text{K}^{-1}\). (a) Calculate the temperature at which the oxide would start to decompose spontaneously (i.e., \(\Delta G^{\circ}=0\)). (b) The waste treatment plant operates at \(1200\ \text{K}\). Will the oxide decompose at this temperature? (c) Considering the reaction \(\text{XO}+\text{C}\rightarrow\text{X}+\text{CO}\) and that the standard Gibbs free energy for \(\text{C}+\frac{1}{2}\text{O}_2\rightarrow\text{CO}\) at \(1200\ \text{K}\) is \(-110\ \text{kJ mol}^{-1}\), state whether carbon can reduce the oxide at the plant temperature.

Answer Options

A. Yes; the oxide requires about \\(2.0\\times10^{3}\\ \text{K}\\) to decompose, so at \\(1200\\ \text{K}\\) it will decompose slowly, allowing carbon reduction.
B. Yes; the oxide requires only about \\(1.5\\times10^{3}\\ \text{K}\\) to decompose, so at \\(1200\\ \text{K}\\) it will partially decompose and can be reduced by carbon.
C. No; the oxide requires about \\(3.5\\times10^{3}\\ \text{K}\\) to decompose, so at \\(1200\\ \text{K}\\) it remains stable, but carbon can still reduce it due to the favorable CO formation.
Correct Answer D. No; the oxide requires about \(2.92\times10^{3}\ \text{K}\) to decompose, so at \(1200\ \text{K}\) it remains stable and cannot be reduced by carbon.
Correct Answer
D
Correct Option:
No; the oxide requires about \(2.92\times10^{3}\ \text{K}\) to decompose, so at \(1200\ \text{K}\) it remains stable and cannot be reduced by carbon.

About This Question

This is Neco 2017 Chemistry Question 41. It is one of the objective questions from the 2017 Neco Chemistry examination.

Difficulty level: Hard .

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