Gce Model Questions Vol1 2025 Chemistry Question 4

Practice objective / multiple choice question 4 from the 2025 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2025 Chemistry Objective / Multiple Choice Medium Difficulty
Question 4 GCE_MODEL_QUESTIONS_VOL1 • 2025 • CHEMISTRY • objective

In acidic solution the following redox process occurs: \( \mathrm{MnO_4^- + C_2O_4^{2-} \rightarrow Mn^{2+} + CO_2} \). The standard reduction potentials are \( E^\circ(\mathrm{MnO_4^- / Mn^{2+}}) = +1.51\ \text{V} \) and \( E^\circ(\mathrm{C_2O_4^{2-} / CO_2}) = +0.49\ \text{V} \). (a) Balance the overall redox equation. (b) Calculate the standard cell potential \( E^\circ_{\text{cell}} \). (c) If the reaction is carried out at 25 °C with concentrations \([ \mathrm{MnO_4^-} ] = 0.010\ \text{M}\), \([ \mathrm{C_2O_4^{2-}} ] = 0.020\ \text{M}\), and \([ \mathrm{H^+} ] = 0.100\ \text{M}\), determine the cell potential using the Nernst equation (assume all other species have unit activity).

Answer Options

A. Balanced equation: 2 MnO₄⁻ + 5 C₂O₄²⁻ + 16 H⁺ → 2 Mn²⁺ + 10 CO₂ + 8 H₂O; E°cell = 1.12 V; E ≈ 0.95 V at the stated concentrations.
B. Balanced equation: 2 MnO₄⁻ + 3 C₂O₄²⁻ + 12 H⁺ → 2 Mn²⁺ + 6 CO₂ + 6 H₂O; E°cell = 0.92 V; E ≈ 0.78 V at the stated concentrations.
C. Balanced equation: 1 MnO₄⁻ + 5 C₂O₄²⁻ + 8 H⁺ → 1 Mn²⁺ + 10 CO₂ + 4 H₂O; E°cell = 1.02 V; E ≈ 0.90 V at the stated concentrations.
Correct Answer D. Balanced equation: 2 MnO₄⁻ + 5 C₂O₄²⁻ + 16 H⁺ → 2 Mn²⁺ + 10 CO₂ + 8 H₂O; E°cell = 1.02 V; E ≈ 0.85 V at the stated concentrations.
Correct Answer
D
Correct Option:
Balanced equation: 2 MnO₄⁻ + 5 C₂O₄²⁻ + 16 H⁺ → 2 Mn²⁺ + 10 CO₂ + 8 H₂O; E°cell = 1.02 V; E ≈ 0.85 V at the stated concentrations.

About This Question

This is Gce Model Questions Vol1 2025 Chemistry Question 4. It is one of the objective questions from the 2025 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Medium .

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