Gce Model Questions Vol1 2025 Chemistry Question 31

Practice objective / multiple choice question 31 from the 2025 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2025 Chemistry Objective / Multiple Choice Hard Difficulty
Question 31 GCE_MODEL_QUESTIONS_VOL1 • 2025 • CHEMISTRY • objective

A sample of 2‑methyl‑2‑butanol (C₆H₁₄O) weighing 5.00 g is treated with potassium dichromate in acidic medium. The oxidation (3 C₆H₁₄O + K₂Cr₂O₇ + 4 H₂SO₄ → 3 C₆H₁₂O + K₂SO₄ + Cr₂(SO₄)₃ + 7 H₂O) gives the ketone 3‑methyl‑2‑butanone, while any remaining alcohol can undergo dehydration (C₆H₁₄O → C₆H₁₂ + H₂O) using one mole of H₂SO₄ per mole of alcohol. The experiment uses 0.020 mol of K₂Cr₂O₇ and a total of 0.060 mol of H₂SO₄. Assuming the oxidation proceeds until either the dichromate or H₂SO₄ is exhausted and the remaining alcohol then dehydrates, calculate the mass of 3‑methyl‑2‑butanone obtained (give your answer to three significant figures).

Answer Options

A. 2.45 g
Correct Answer B. 2.86 g
C. 3.10 g
D. 1.87 g
Correct Answer
B
Correct Option:
2.86 g

About This Question

This is Gce Model Questions Vol1 2025 Chemistry Question 31. It is one of the objective questions from the 2025 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Hard .

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