Gce Model Questions Vol1 2024 Chemistry Question 6

Practice essay / theory question 6 from the 2024 Gce Model Questions Vol1 Chemistry examination. This question covers States of Matter .

Gce Model Questions Vol1 2024 Chemistry Essay / Theory
Topic: States of Matter
Question 6 GCE_MODEL_QUESTIONS_VOL1 • 2024 • CHEMISTRY • essay

A sealed rigid container of volume 5.00 L contains 0.80 mol of nitrogen gas (N₂) at 298 K. The container is then heated to 350 K. (a) Calculate the final pressure of the gas, assuming ideal behaviour. (b) Using the van der Waals constants for N₂ (a = 1.39 L²·atm·mol⁻², b = 0.0391 L·mol⁻¹), calculate the corrected pressure at 350 K. (c) Explain, with reference to intermolecular forces and molecular volume, why the real pressure differs from the ideal pressure. (d) Sketch a qualitative P–T phase diagram for nitrogen, indicating the positions of the initial and final states and the critical point.

Question Parts

( a )
Calculate the final pressure of the gas, assuming ideal behaviour.
( b )
Using the van der Waals constants for N₂ (a = 1.39 L²·atm·mol⁻², b = 0.0391 L·mol⁻¹), calculate the corrected pressure at 350 K.
( c )
Explain, with reference to intermolecular forces and molecular volume, why the real pressure differs from the ideal pressure.
( d )
Sketch a qualitative P–T phase diagram for nitrogen, indicating the positions of the initial (298 K, 3.7 atm) and final (350 K, 3.6 atm) states and the critical point.

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About This Question

This is Gce Model Questions Vol1 2024 Chemistry Question 6. It is one of the essay questions from the 2024 Gce Model Questions Vol1 Chemistry examination.

The question covers States of Matter .

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