Gce Model Questions Vol1 2021 Chemistry Question 38

Practice objective / multiple choice question 38 from the 2021 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2021 Chemistry Objective / Multiple Choice Hard Difficulty
Question 38 GCE_MODEL_QUESTIONS_VOL1 • 2021 • CHEMISTRY • objective

Isobutyric acid (2‑methylpropanoic acid, molar mass 88 g mol⁻¹) is converted to its acid chloride with excess thionyl chloride and then reacted with aniline (molar mass 93.13 g mol⁻¹) to give the corresponding amide. If 5.00 g of the acid and 6.00 g of aniline are used, (a) identify the limiting reagent, (b) calculate the theoretical mass of the amide product (molar mass 163 g mol⁻¹), (c) a laboratory isolation yields 5.20 g of product; compute the percent yield, and (d) state the functional group present in the product and explain why an IR absorption near 1650 cm⁻¹ is observed.

Answer Options

A. Limiting reagent: isobutyric acid; theoretical mass 9.26 g; percent yield 70.0 %; product contains a ketone (C=O stretch ≈1710 cm⁻¹)
Correct Answer B. Limiting reagent: isobutyric acid; theoretical mass 9.26 g; percent yield 56.1 %; product contains an amide (C=O stretch ≈1650 cm⁻¹)
C. Limiting reagent: aniline; theoretical mass 8.12 g; percent yield 64.5 %; product contains an amide (C=O stretch ≈1650 cm⁻¹)
D. Limiting reagent: isobutyric acid; theoretical mass 10.5 g; percent yield 49.5 %; product contains an amide (C=O stretch ≈1650 cm⁻¹)
Correct Answer
B
Correct Option:
Limiting reagent: isobutyric acid; theoretical mass 9.26 g; percent yield 56.1 %; product contains an amide (C=O stretch ≈1650 cm⁻¹)

About This Question

This is Gce Model Questions Vol1 2021 Chemistry Question 38. It is one of the objective questions from the 2021 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Hard .

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