Gce Model Questions Vol1 2021 Chemistry Question 3

Practice objective / multiple choice question 3 from the 2021 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2021 Chemistry Objective / Multiple Choice Hard Difficulty
Question 3 GCE_MODEL_QUESTIONS_VOL1 • 2021 • CHEMISTRY • objective

A buffer solution is prepared by dissolving \(0.20\ \text{mol}\) of acetic acid (\(\mathrm{CH_3COOH}\)) and \(0.15\ \text{mol}\) of sodium acetate (\(\mathrm{CH_3COONa}\)) in \(1.0\ \text{L}\) of water. The acid dissociation constant is \(K_a = 1.8\times10^{-5}\). (a) Calculate the initial pH of the buffer. (b) How many moles of \(0.10\ \text{M}\) HCl must be added to lower the pH to 4.50? (c) After the addition, what is the new ratio \([\mathrm{A^-}]/[\mathrm{HA}]\) in the solution?

Answer Options

A. Initial pH = 4.80; add 0.0250 mol HCl; new ratio [A⁻]/[HA] = 0.62
Correct Answer B. Initial pH = 4.62; add 0.0228 mol HCl; new ratio [A⁻]/[HA] = 0.571
C. Initial pH = 4.45; add 0.0185 mol HCl; new ratio [A⁻]/[HA] = 0.45
D. Initial pH = 4.30; add 0.0200 mol HCl; new ratio [A⁻]/[HA] = 0.50
Correct Answer
B
Correct Option:
Initial pH = 4.62; add 0.0228 mol HCl; new ratio [A⁻]/[HA] = 0.571

About This Question

This is Gce Model Questions Vol1 2021 Chemistry Question 3. It is one of the objective questions from the 2021 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Hard .

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