Gce Model Questions Vol1 2019 Chemistry Question 39

Practice objective / multiple choice question 39 from the 2019 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2019 Chemistry Objective / Multiple Choice Medium Difficulty
Question 39 GCE_MODEL_QUESTIONS_VOL1 • 2019 • CHEMISTRY • objective

A galvanic cell is assembled with a \(\mathrm{Cu^{2+}/Cu}\) electrode (standard reduction potential \(E^{\circ}=+0.34\) V) and a \(\mathrm{Fe^{2+}/Fe}\) electrode (standard reduction potential \(E^{\circ}=-0.44\) V). Both half‑cells contain 0.010 mol dm⁻³ of their respective metal ions at 25 °C.\n\n(i) Write the overall cell reaction and calculate the standard cell potential \(E^{\circ}_{\text{cell}}\).\n(ii) If the concentration of \(\mathrm{Cu^{2+}}\) is increased to 0.10 mol dm⁻³ while \(\mathrm{Fe^{2+}}\) remains at 0.010 mol dm⁻³, calculate the cell potential using the Nernst equation.\n(iii) State the direction of spontaneous electron flow in both cases.

Answer Options

A. E°cell = 0.88 V; after concentration change E ≈ 0.91 V; electrons flow from Fe to Cu in both cases.
B. E°cell = 0.78 V; after concentration change E ≈ 0.75 V; electrons flow from Cu to Fe in both cases.
C. E°cell = 0.68 V; after concentration change E ≈ 0.71 V; electrons flow from Fe to Cu in both cases.
Correct Answer D. E°cell = 0.78 V; after concentration change E ≈ 0.81 V; electrons flow from Fe to Cu in both cases.
Correct Answer
D
Correct Option:
E°cell = 0.78 V; after concentration change E ≈ 0.81 V; electrons flow from Fe to Cu in both cases.

About This Question

This is Gce Model Questions Vol1 2019 Chemistry Question 39. It is one of the objective questions from the 2019 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Medium .

Master the Exam!

You've seen a preview, but there are thousands more questions plus AI tutor to break down complex solutions.

Unlock Full Access Available for Android & Windows
Chat with Support