Gce Model Questions Vol1 2018 Chemistry Question 45

Practice objective / multiple choice question 45 from the 2018 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2018 Chemistry Objective / Multiple Choice Hard Difficulty
Question 45 GCE_MODEL_QUESTIONS_VOL1 • 2018 • CHEMISTRY • objective

The intrinsic viscosity \([\eta]\) of a poly(vinyl chloride) (PVC) solution in tetrahydrofuran at 25 °C is measured as 0.85 dL·g⁻¹. For PVC the Mark-Houwink relationship is \([\eta] = K M^{a}\) with \(K = 1.2 \times 10^{-4}\ \text{dL g}^{-1}\) and \(a = 0.70\). (i) Calculate the number‑average molecular weight \(M_{n}\) of the polymer. (ii) Given that the molar mass of the repeating unit C₂H₃Cl is 62.5 g·mol⁻¹, calculate the average degree of polymerisation (DP).

Answer Options

A. Mₙ ≈ 2.5×10⁵ g·mol⁻¹; DP ≈ 4.0×10³
Correct Answer B. Mₙ ≈ 3.2×10⁵ g·mol⁻¹; DP ≈ 5.1×10³
C. Mₙ ≈ 4.0×10⁵ g·mol⁻¹; DP ≈ 6.4×10³
D. Mₙ ≈ 3.2×10⁶ g·mol⁻¹; DP ≈ 5.1×10⁴
Correct Answer
B
Correct Option:
Mₙ ≈ 3.2×10⁵ g·mol⁻¹; DP ≈ 5.1×10³

About This Question

This is Gce Model Questions Vol1 2018 Chemistry Question 45. It is one of the objective questions from the 2018 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Hard .

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