POST UTME PAN-ATLANTIC UNIVERSITY 2025 Chemistry | Objective
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Question 1
A solution of hydrochloric acid (HCl) is prepared by dissolving 25 g of the acid in 250 mL of water. What is the concentration of the solution in g/L?
Question 2
A 25.0 mL sample of 0.150 M HCl is mixed with a 25.0 mL sample of 0.150 M NaOH. What is the concentration of the resulting solution?
Question 3
A 2.50 g sample of a compound containing only C, H, and O is analyzed by combustion. The CO2 produced is collected and found to have a mass of 1.25 g. The H2O produced is collected and found to have a mass of 0.500 g. What is the empirical formula of the compound?
Question 4
A sample of oxygen (O2) is collected over water at a temperature of 20°C and a pressure of 1 atm. What is the volume of the gas at STP?
Question 5
A 2.00 g sample of a subs\tance is dissolved in 100.0 mL of water. What is the molarity of the solution?
Question 6
Calculate the s\tandard enthalpy change \( ΔH^circ \) for the reaction: 2Al(s) + Fe2O3(s) → 2Fe(s) + Al2O3(s). The s\tandard enthalpy of formation \( ΔH^circ_f \) values are: ΔH^circ_f(Al2O3(s)) = -1675.7 kJ/mol, ΔH^circ_f(Al(s)) = 0 kJ/mol, ΔH^circ_f(Fe(s)) = 0 kJ/mol, and ΔH^circ_f(Fe2O3(s)) = -824.2 kJ/mol.
Question 7
A metal (M) reacts with oxygen (O2) to form a basic oxide (MO). If 2.5 g of the metal is heated in air, and 1.5 g of the oxide is formed, what is the percentage yield of the reaction?
Question 8
A 5.00-g sample of a non-metallic compound is dissolved in 100 mL of a solvent. The molar mass of the compound is 200 g/mol. Calculate the concentration of the compound in the solution.
Question 9
In a reaction between sodium (Na) and chlorine (Cl2), what is the expected product?
Question 10
A metal (M) reacts with oxygen to form a basic oxide (MO). The reaction is: 4M + 3O2 → 2MO. If 2.50 g of M reacts with 1.50 g of O2, what is the mass of M used?
Question 11
A metal (M) has an atomic radius of 250 pm. If the metal forms a +3 ion, what is the radius of the ion?
Question 12
Determine the s\tandard Gibbs free energy change (ΔG°) for the reaction: 2Ag+(aq) + 2I-(aq) → 2Ag(s) + I2(s) at 298 K, given that the s\tandard enthalpy change (ΔH°) is -187.2 kJ/mol and the s\tandard entropy change (ΔS°) is -278.0 J/mol·K.
Question 13
The rate cons\tant for the decomposition of a certain compound is 2.50 × 10⁻² s⁻¹ at 25°C. If the initial concentration of the compound is 0.100 M, calculate the concentration of the compound after 5.00 minutes.
Question 14
A solution of sodium chloride (NaCl) is prepared by dissolving 35 g of the salt in 250 mL of water. What is the concentration of the solution in g/L?
Question 15
A 2.00 g sample of a subs\tance is burned in a bomb calorimeter. The temperature of the calorimeter increases by 10.0 K. What is the heat of combustion of the subs\tance?
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