POST UTME CHRISTOPHER UNIVERSITY 2021 Chemistry | Objective

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Question 1
Determine the pH of a 0.1 M solution of HCl at 25°C. The dissociation cons\tant of HCl is 10^\( -7 \).
A. 1
B. 2
C. 3
Correct D. 4

Correct Answer: D

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Question 2
A diagram of a titration setup is shown below. If 25 mL of 0.1 M NaOH is added to 25 mL of 0.1 M HCl, what is the pH of the resulting solution?
A. 1
Correct B. 2
C. 3
D. 4

Correct Answer: B

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Question 3
A solution contains 0.1 M HCl and 0.1 M NaOH. What is the pH of the solution after 25 mL of 0.1 M HCl is added to 25 mL of 0.1 M NaOH?
A. 1
B. 2
C. 3
Correct D. 4

Correct Answer: D

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Question 4
A diagram of a periodic table is shown below. Identify the element with atomic number 8.
Correct A. Oxygen
B. Nitrogen
C. Carbon
D. Hydrogen

Correct Answer: A

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Question 5
A diagram of a gas law setup is shown below. If the pressure of a gas is doubled and the temperature is tripled, what is the new volume of the gas?
A. 1
B. 2
C. 3
Correct D. 4

Correct Answer: D

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Question 6
Determine the s\tandard enthalpy of formation of CaCO3(s) from the following data: ΔHf(CaO(s)) = -635.09 kJ/mol, ΔHf(CO2(g)) = -393.51 kJ/mol. Assume the reaction is CaO(s) + CO2(g) → CaCO3(s).
Correct A. -1207.6 kJ/mol
B. -1207.6 kJ/mol
C. -1207.6 kJ/mol
D. -1207.6 kJ/mol

Correct Answer: A

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Question 7
A 0.5 M solution of NaCl is prepared by dissolving 2.5 g of NaCl in 1 L of water. What is the molarity of the solution?
Correct A. 0.5 M
B. 0.5 M
C. 0.5 M
D. 0.5 M

Correct Answer: A

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Question 8
The solubility of AgCl in water is 1.2 × 10^\( -5 \) M at 25°C. What is the concentration of Ag+ ions in a saturated solution?
Correct A. 1.2 × 10^\( -5 \) M
B. 1.2 × 10^\( -5 \) M
C. 1.2 × 10^\( -5 \) M
D. 1.2 × 10^\( -5 \) M

Correct Answer: A

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Question 9
A sample of a gas has a volume of 2.5 L at a pressure of 1.5 atm and a temperature of 298 K. What is the volume of the gas at a pressure of 3.0 atm and a temperature of 323 K?
Correct A. 3.2 L
B. 3.2 L
C. 3.2 L
D. 3.2 L

Correct Answer: A

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Question 10
The s\tandard enthalpy of formation of CO2(g) is -393.51 kJ/mol. What is the s\tandard enthalpy of formation of CO(g)?
Correct A. -110.5 kJ/mol
B. -110.5 kJ/mol
C. -110.5 kJ/mol
D. -110.5 kJ/mol

Correct Answer: A

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Question 11
Determine the number of moles of oxygen gas (O2) produced at s\tandard temperature and pressure (STP) when 2.5 moles of hydrogen gas (H2) react with oxygen gas according to the equation: 2H2 + O2 → 2H2O.
A. 1.25 moles
B. 2.5 moles
Correct C. 5.0 moles
D. 10.0 moles

Correct Answer: C

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Question 12
A 2.5 M solution of HCl is titrated with a 1.0 M solution of NaOH. If 25 mL of NaOH is required to reach the equivalence point, what is the number of moles of HCl in the original solution?
A. 0.0625 moles
Correct B. 0.125 moles
C. 0.25 moles
D. 0.5 moles

Correct Answer: B

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Question 13
The reaction between H2 and O2 to form H2O is exothermic. If 5.0 moles of H2 react with oxygen gas to form 10.0 moles of H2O, what is the change in entropy (ΔS) for the reaction?
A. -20 J/K
B. -40 J/K
Correct C. -60 J/K
D. -80 J/K

Correct Answer: C

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Question 14
A 1.0 M solution of NaOH is titrated with a 2.0 M solution of HCl. If 25 mL of HCl is required to reach the equivalence point, what is the number of moles of NaOH in the original solution?
A. 0.125 moles
Correct B. 0.25 moles
C. 0.5 moles
D. 1.0 moles

Correct Answer: B

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Question 15
The reaction between H2 and O2 to form H2O is exothermic. If 10.0 moles of H2 react with oxygen gas to form 20.0 moles of H2O, what is the change in entropy (ΔS) for the reaction?
A. -40 J/K
B. -60 J/K
Correct C. -80 J/K
D. -100 J/K

Correct Answer: C

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Question 16
A 0.1 M solution of a monoprotic acid is titrated with 0.1 M NaOH. If the initial pH of the acid is 2.5, what is the pH after the addition of 20 mL of NaOH?
A. 3.5
B. 4.5
Correct C. 5.5
D. 6.5

Correct Answer: C

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Question 17
A 10 mL sample of a solution containing a mixture of NaCl and Na2SO4 is electrolyzed u\sing a current of 2 A for 5 minutes. If the initial concentration of Na+ ions is 0.1 M, what is the concentration of Na+ ions after electrolysis?
A. 0.05 M
B. 0.1 M
Correct C. 0.15 M
D. 0.2 M

Correct Answer: C

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Question 18
A 2 L sample of a gas at 300 K and 1 atm is expanded to 5 L at cons\tant temperature. What is the new pressure of the gas?
A. 0.2 atm
B. 0.4 atm
Correct C. 0.6 atm
D. 0.8 atm

Correct Answer: C

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Question 19
A 0.1 M solution of a weak acid HA is titrated with 0.1 M NaOH. If the initial pH of the acid is 3.5, what is the pH after the addition of 20 mL of NaOH?
A. 4.5
Correct B. 5.5
C. 6.5
D. 7.5

Correct Answer: B

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Question 20
A 10 mL sample of a solution containing a mixture of NaCl and Na2SO4 is electrolyzed u\sing a current of 2 A for 5 minutes. If the initial concentration of Na+ ions is 0.1 M, what is the concentration of Na+ ions after electrolysis?
A. 0.05 M
B. 0.1 M
Correct C. 0.15 M
D. 0.2 M

Correct Answer: C

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Question 21
In a reaction between zinc metal and copper(II) sulfate solution, the reaction is represented by the equation: Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s). If 2.50 g of zinc metal is added to 100 mL of 0.100 M copper(II) sulfate solution, what is the limiting reac\tant?
Correct A. Zinc metal
B. Copper(II) sulfate solution
C. Zinc sulfate solution
D. Copper metal

Correct Answer: A

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Question 22
A 1.00 L sample of a gas at 27°C and 1.00 atm is collected over water at 25°C. If the vapor pressure of water at 25°C is 23.8 torr, what is the partial pressure of the gas?
A. 1.00 atm
Correct B. 0.980 atm
C. 1.02 atm
D. 1.05 atm

Correct Answer: B

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Question 23
A solution contains 0.0500 M FeCl3 and 0.0500 M NaOH. What is the concentration of Fe(OH)3 formed after the reaction is complete?
A. 0.0500 M
B. 0.100 M
Correct C. 0.150 M
D. 0.200 M

Correct Answer: C

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Question 24
A 2.00 L sample of a gas at 25°C and 1.00 atm is collected over water at 25°C. If the vapor pressure of water at 25°C is 23.8 torr, what is the partial pressure of the gas?
A. 1.00 atm
Correct B. 0.980 atm
C. 1.02 atm
D. 1.05 atm

Correct Answer: B

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Question 25
A 1.00 L sample of a gas at 27°C and 1.00 atm is collected over water at 25°C. If the vapor pressure of water at 25°C is 23.8 torr, what is the partial pressure of the gas?
A. 1.00 atm
Correct B. 0.980 atm
C. 1.02 atm
D. 1.05 atm

Correct Answer: B

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