POST UTME BOWEN UNIVERSITY 2025 Chemistry | Objective
Practice these randomly selected questions to test your readiness.
Question 1
A 2.5 M solution of HCl is electrolyzed u\sing a platinum electrode. If the electrolysis is carried out for 2 hours, and the volume of H2 gas produced is 2.5 L at 25°C and 1 atm, calculate the number of moles of H2 gas produced.
Question 2
A polymer has a molecular weight of 100,000 g/mol and a degree of polymerization of 500. Calculate the molar mass of the repeating unit.
Question 3
A polymer is composed of repeating units of the following structure: CH2-CH2-CH2-CH2. If the polymer has a molecular weight of 100,000 g/mol, and the repeating unit has a molecular weight of 28 g/mol, calculate the degree of polymerization (DP).
Question 4
A 2.00-L sample of a gas at 25°C and 1.00 atm is collected over water at 25°C. If the vapor pressure of water at 25°C is 23.8 torr, what is the partial pressure of the gas?
Question 5
A 1.00-L sample of a solution containing 0.100 M NaCl is mixed with 1.00 L of a solution containing 0.0500 M CaCl2. What is the concentration of the resulting solution?
Question 6
A 2.00-g sample of a subs\tance is placed in a 100-mL flask and heated to 100°C. The pressure of the gas is measured to be 1.00 atm. What is the number of moles of gas present?
Question 7
Determine the rate cons\tant (k) for the first-order reaction: A → B, given that the initial concentration of A is 0.5 M and the concentration of A after 2 hours is 0.2 M. The rate cons\tant is related to the half-life \( t1/2 \) by the equation: ln(2) = kt1/2.
Question 8
A 2.50-g sample of a compound containing only C, H, and O is analyzed by combustion. The CO2 produced is 1.25 g, and the H2O produced is 0.500 g. What is the empirical formula of the compound?
Question 9
The half-reaction for the oxidation of S2- to S is: S2- → S + ?
Question 10
Determine the number of moles of ΔH2O formed when 2.50 g of H2SO4 reacts with 3.00 g of NaOH in a reaction that proceeds to completion.
Question 11
The s\tandard enthalpy of formation of CO2(g) is -393.5 kJ/mol. Calculate the s\tandard enthalpy of formation of H2CO3(s) given that the s\tandard enthalpy of formation of H2O(l) is -285.8 kJ/mol and the s\tandard enthalpy of formation of CO(g) is -110.5 kJ/mol.
Question 12
A solution of 0.1 M NaCl is prepared by dissolving 1.0 g of NaCl in 100 mL of water. If the density of the solution is 1.0 g/mL, calculate the concentration of NaCl in the solution.
Question 13
A gas is collected over water at 25°C and 1 atm. If the volume of the gas is 2.5 L, and the vapor pressure of water at 25°C is 0.0313 atm, calculate the partial pressure of the gas.
Question 14
The half-reaction for the reduction of Cu2+ to Cu is: Cu2+ + e- → Cu+ + ?
Question 15
Determine the pH of a 0.1 M solution of HCl.
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