Igcse Model Questions Vol1 2018 Chemistry Question 9

Practice essay / theory question 9 from the 2018 Igcse Model Questions Vol1 Chemistry examination. This question covers Redox reactions, Electrochemistry .

Igcse Model Questions Vol1 2018 Chemistry Essay / Theory
Topics: Redox reactions Electrochemistry
Question 9 IGCSE_MODEL_QUESTIONS_VOL1 • 2018 • CHEMISTRY • essay

A piece of clean zinc metal is immersed in 250 cm³ of a 0.010 mol dm⁻³ copper(II) sulphate solution at 25 °C. The reaction proceeds until the solution becomes colourless. The standard reduction potentials are: \[\text{Cu}^{2+}+2e^-\rightarrow\text{Cu}\quad E^{\circ}=+0.34\text{ V}\] \[\text{Zn}^{2+}+2e^-\rightarrow\text{Zn}\quad E^{\circ}=-0.76\text{ V}\] During the experiment a constant current of 0.50 A is passed for 30 minutes. Answer the following:

Question Parts

( a )
Write the balanced overall redox equation for the reaction between zinc metal and copper(II) ions.
( b )
Write the two half‑reactions (oxidation and reduction) and state which species acts as the oxidising agent and which as the reducing agent.
( c )
Calculate the mass of copper metal deposited on the zinc surface after the 30‑minute period. Assume 100 % current efficiency.
( d )
Determine the standard electromotive force (E°cell) of the Zn|Zn^{2+} || Cu^{2+}|Cu cell.
( e )
Explain qualitatively how the cell potential would change if the concentration of Cu^{2+} ions were halved, using the Nernst equation (no numerical calculation required).

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About This Question

This is Igcse Model Questions Vol1 2018 Chemistry Question 9. It is one of the essay questions from the 2018 Igcse Model Questions Vol1 Chemistry examination.

The question covers Redox reactions, Electrochemistry .

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