Gce Model Questions Vol1 2017 Chemistry Question 28

Practice objective / multiple choice question 28 from the 2017 Gce Model Questions Vol1 Chemistry examination.

Gce Model Questions Vol1 2017 Chemistry Objective / Multiple Choice Hard Difficulty
Question 28 GCE_MODEL_QUESTIONS_VOL1 • 2017 • CHEMISTRY • objective

Rainwater forms when atmospheric gases dissolve in water. The partial pressure of CO₂ is \(4.0 \times 10^{-4}\) atm and its Henry's law constant is \(k_H = 3.3 \times 10^{-2}\ \text{mol L}^{-1}\text{atm}^{-1}\). CO₂ hydrates to give carbonic acid with first dissociation constant \(K_{a1}=4.3 \times 10^{-7}\). The partial pressure of SO₂ is \(1.0 \times 10^{-5}\) atm and its Henry's law constant is \(k_H = 1.2\ \text{mol L}^{-1}\text{atm}^{-1}\); the first dissociation constant of H₂SO₃ is \(K_a = 1.2 \times 10^{-2}\). Assuming both acids dissociate independently and activity coefficients are unity, calculate the pH of the resulting rainwater.

Answer Options

A. pH ≈ 4.30
Correct Answer B. pH ≈ 4.71
C. pH ≈ 3.95
D. pH ≈ 5.12
Correct Answer
B
Correct Option:
pH ≈ 4.71

About This Question

This is Gce Model Questions Vol1 2017 Chemistry Question 28. It is one of the objective questions from the 2017 Gce Model Questions Vol1 Chemistry examination.

Difficulty level: Hard .

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