WAEC 2023 Chemistry | Objective

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Question 1 View Details
Which of the following laws or theory cannot be explained by the application of the kinetic theory of gases?
Correct A. Dalton's atomic theory
B. Charles' law
C. Gay-lussac's law
D. Boyle's law

Correct Answer: A

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Question 2 View Details
The primary component of natural gas is
A. butane
B. ethane
Correct C. methane
D. propane

Correct Answer: C

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Question 3 View Details
Thermal cracking of alkanes usually
Correct A. involves decomposition
B. is an exothermic process
C. produces only small alkanes
D. requires hydrogen

Correct Answer: A

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Question 4 View Details
Carbon is deposited in the exhaust pipes of cars because of
A. contamination of petrol with diesel
B. presence of carbon in petrol
C. presence of additives in petrol
Correct D. incomplete combustion of petrol

Correct Answer: D

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Question 5 View Details
How many moles of copper would be deposited by passing 1 Faraday of electricity through a \( \mathrm{CuCl}_{2} \) solution?
A. 2
Correct B. 1
C. 0.5
D. 0.25

Correct Answer: B

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Question 6 View Details
Alkenes can be manufactured by
A. addition of hydrogen to unsaturated vegetable oils
Correct B. the cracking of hydrocarbons
C. polymerization reactions
D. the combustion of alkanes

Correct Answer: B

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Question 7 View Details
Petrochemistry is an example of
A. pure chemistry
Correct B. applied chemistry
C. biochemistry
D. environmental chemistry

Correct Answer: B

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Question 8 View Details
Species that occur in a reaction pathway but not in the overall reaction are known as
A. products
B. inhibitors
C. reactants
Correct D. intermediates

Correct Answer: D

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Question 9 View Details
Which of the following statements is correct?
A. An alkane with 49 carbon atoms contains 100 hydrogen atoms
B. Addition reactions occur between alkanes and chlorine
C. Butane has a lower boiling point than propane
Correct D. Pentane has five isomers

Correct Answer: D

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Question 10 View Details
The best indicator to use for the titration of ethanoic acid with sodium hydroxide is
A. methyl red
B. methyl orange
Correct C. phenolphthalein
D. screened methyl orange

Correct Answer: C

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Question 11 View Details
The reduction half equation of the following reaction is:\[ \mathrm{Zn}_{(s)}+\mathrm{CuSO}_{4(aq)} \rightarrow \mathrm{ZnSO}_{4(aq)}+\mathrm{Cu}_{(s)} \]
A. \( \mathrm{CuSO}_{4(s)}+\mathrm{H}_{2}\mathrm{O}_{(l)} \rightarrow \mathrm{C}_{(aq)}^{2+}+\mathrm{SO}_{(aq)}^{2-} \)
B. \( \mathrm{Cu}_{(aq)}^{2+}+2 \mathrm{e} \rightarrow \mathrm{Cu}_{(s)} \)
Correct C. \( \mathrm{Cu}_{(aq)}^{2+}+\mathrm{e} \rightarrow \mathrm{Cu}_{(s)} \)
D. \( \mathrm{Zn}_{(s)} \rightarrow \mathrm{Zn}_{(aq)}^{2+}+2 \mathrm{e} \)

Correct Answer: C

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Question 12 View Details
If \( 100 cm^{3} \) of a saturated solution of sodium tetraoxosulphate (VI) at \( 30^{\circ}C \) contains 10.5 g of the salt, what would be its solubility at this temperature? \( [\mathrm{Na}_{2}\mathrm{SO}_{4}=142] \)
A. 0.57 mol \( dm^{-3} \)
Correct B. 0.60 mol \( dm^{-3} \)
C. 0.74 mol \( dm^{-3} \)
D. 2.15 mol \( dm^{-3} \)

Correct Answer: B

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Question 13 View Details
An example of a crystalline substance that does not possess water of crystallization is
Correct A. potassium trioxonitrate (V)
B. sodium trioxocarbonate (IV)
C. iron (II) tetraoxosulphate (VI)
D. sodium tetraoxosulphate (VI)

Correct Answer: A

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Question 14 View Details
The salt solution formed from a reaction between ethanoic acid and sodium hydroxide solution would be
A. basic
B. acidic
Correct C. neutral
D. amphoteric

Correct Answer: C

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Question 15 View Details
Which of the following reactions represents the hydrolysis of an alkanoate?
A. \( \mathrm{CH}_{3}\mathrm{COOH} + \mathrm{C}_{2}\mathrm{H}_{5}\mathrm{OH} \stackrel{H^{+}}{\rightleftharpoons} \mathrm{CH}_{3}\mathrm{COOC}_{2}\mathrm{H}_{5} + \mathrm{H}_{2}\mathrm{O} \)
Correct B. \( \mathrm{CH}_{3}\mathrm{COOC}_{2}\mathrm{H}_{5} + \mathrm{H}_{2}\mathrm{O} \xrightarrow{H^{+}} \mathrm{CH}_{3}\mathrm{COO}^{-} + \mathrm{CH}_{3}\mathrm{CH}_{2}\mathrm{OH} \)
C. \( \mathrm{CH}_{3}\mathrm{COOCH}_{2}\mathrm{CH}_{3}\mathrm{CH}_{3} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{CH}_{3}\mathrm{COOH} + \mathrm{CH}_{3}\mathrm{CH}_{2}\mathrm{OH} \)
D. \( \mathrm{CH}_{3}\mathrm{COOH} + \mathrm{OH}^{-} \stackrel{H^{+}}{\rightleftharpoons} \mathrm{CH}_{3}\mathrm{COO}^{-} + \mathrm{H}_{2}\mathrm{O} \)

Correct Answer: B

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Question 16 View Details
Which of the following statements about the collision theory is correct?
A. All collisions bring about reactions
Correct B. Rate of reaction is proportional to the number of effective collisions
C. Collision of molecules will split the molecules to react
D. Ineffective collision brings about chemical reaction

Correct Answer: B

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Question 17 View Details
Why are \( \mathrm{H}_{2}\mathrm{SO}_{4} \) and \( \mathrm{CaCl}_{2} \) not suitable for drying ammonia gas? They
A. are corrosive
B. are poisonous
Correct C. react with the gas
D. pollute the gas

Correct Answer: C

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Question 18 View Details
Which of the following equations does not illustrate correctly one of the reactions of chlorine?
A. \( \mathrm{H}_{2}\mathrm{S} + \mathrm{Cl}_{2} \rightarrow 2 \mathrm{HCl} + \mathrm{S} \)
B. \( \mathrm{Cl}_{2} + 2 \mathrm{NaOH} \rightarrow \mathrm{NaCl} + \mathrm{NaClO} + \mathrm{H}_{2}\mathrm{O} \)
Correct C. \( \mathrm{Cl}_{2} + 2 \mathrm{NaF} \rightarrow 2 \mathrm{NaCl} + \mathrm{F}_{2} \)
D. \( \mathrm{Ca} (\mathrm{OH})_{2} + \mathrm{Cl}_{2} \rightarrow \mathrm{CaOCl}_{2} + \mathrm{H}_{2}\mathrm{O} \)

Correct Answer: C

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Question 19 View Details
How many unpaired electrons are present in \( { }_{26} \mathrm{Fe}^{3+} \)
A. 2
Correct B. 3
C. 4
D. 5

Correct Answer: B

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Question 20 View Details
Going down group II in the periodic table normally
A. shielding effect decreases
B. melting point increases
C. ionization energy increases
Correct D. electronegativity increases

Correct Answer: D

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Question 21 View Details
Which of the following elements has its valence electrons in the s-orbital?
Correct A. Sodium
B. Carbon
C. Phosphorus
D. Aluminium

Correct Answer: A

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Question 22 View Details
The periodic property that is used to determine whether a covalent molecule is polar or not is
A. atomic radius
B. electron affinity
Correct C. electronegativity
D. ionization energy

Correct Answer: C

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Question 23 View Details
The following steps are scientific methods except
A. analysis
Correct B. open-mindedness
C. experimentation
D. problem identification

Correct Answer: B

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Question 24 View Details
Isoelectronic species have the same number of
Correct A. electrons
B. neutrons
C. protons
D. ions

Correct Answer: A

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Question 25 View Details
An element X has two isotopes, \( { }_{30}^{65} X \) and \( { }_{30}^{66} X \) with relative abundance of 60% and 40% respectively. The relative atomic mass of X is
A. 65.00
Correct B. 65.40
C. 65.50
D. 66.00

Correct Answer: B

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