POST UTME IMS U 2018 Chemistry | Objective
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Question 1
The energy change (ΔE) for a reaction is related to the enthalpy change (ΔH) and the entropy change (ΔS) by the equation ΔE = ΔH - TΔS. If the reaction is \endothermic \( ΔH = 50 kJ/mol \) and the temperature is 298 K, and the entropy change is -0.1 kJ/mol·K, calculate the energy change (ΔE) for the reaction.
Question 2
Calculate the s\tandard enthalpy change for the reaction: 2Al(s) + Fe2O3(s) → 2Fe(s) + Al2O3(s). The s\tandard enthalpy of formation for Al2O3(s) is -1675.7 kJ/mol, and the s\tandard enthalpy of formation for Fe2O3(s) is -824.2 kJ/mol.
Question 3
Sulfur dioxide (SO2) reacts with oxygen to form sulfur trioxide (SO3). Write a balanced equation for this reaction.
Question 4
A 0.1 M solution of a strong acid, HA, has a pH of 2.5. If 10 mL of 0.1 M NaOH is added to 100 mL of the acid solution, what is the pH of the resulting solution?
Question 5
The diagram below shows a titration setup. If 25.0 mL of 0.100 M NaOH is required to reach the equivalence point, what is the concentration of the HCl solution?
Question 6
A sample of a non-metal has a mass of 10.0 g. If the density of the non-metal is 2.50 g/cm3, what is the volume of the non-metal?
Question 7
The diagram below shows a circuit setup. If the current in the circuit is 2.00 A, what is the potential difference across the resistor?
Question 8
A 2.00 g sample of a metal is heated in air to produce a metal oxide. If the mass of the metal oxide produced is 3.00 g, what is the percentage yield of the reaction?
Question 9
A 2.0 g sample of a compound containing only carbon and hydrogen is analyzed by combustion. The volume of CO2 produced is 1.2 L at 25°C and 1 atm. The volume of H2 produced is 0.6 L at the same conditions. What is the empirical formula of the compound?
Question 10
A solution of sulfuric acid (H2SO4) is titrated with a solution of sodium hydroxide (NaOH). The reaction is as follows: H2SO4 + 2NaOH → Na2SO4 + 2H2O. If 25.0 mL of 0.100 M H2SO4 is titrated with 0.500 M NaOH, what is the number of moles of NaOH required to react with 25.0 mL of 0.100 M H2SO4?
Question 11
The reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH) is a classic example of a neutralization reaction. If 25.0 mL of 1.00 M HCl is added to 50.0 mL of 0.500 M NaOH, what is the pH of the resulting solution?
Question 12
A diagram of a cell is shown below. What is the function of the mitochondria?
Question 13
The reaction of hydrogen gas with oxygen gas to form water is represented by the equation 2H_2 + O_2 → 2H_2O. If 1.00 g of hydrogen gas is burned in excess oxygen, and the heat of combustion is found to be -286 kJ/mol, calculate the s\tandard enthalpy of formation \( ΔH_f^\circ \) for water.
Question 14
A 2.00 g sample of a metal carbonate is heated to produce a metal oxide and carbon dioxide gas. If the mass of the metal oxide produced is 1.50 g, what is the molar mass of the metal carbonate?
Question 15
A sample of 0.500 g of an unknown hydrocarbon is burned in a bomb calorimeter, and the heat of combustion is found to be -37.5 kJ/g. If the molar mass of the hydrocarbon is 84.0 g/mol, calculate the s\tandard enthalpy of combustion \( ΔH_c^\circ \) for the hydrocarbon.
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